RDCH 702: Radiochemistry

This lecture covers the utilization of radionuclide properties to determine origin, age, used, and other properties of nuclear material. These isotope properties are defined as signatures of nuclear material, and include concentrations, relative amounts, and ratios. Specific details are provided on forensic signatures related to Pu and actinide isotopics. The signatures arising from reactors, separations, and post-detonation are included. For plutonium production these signatures include reactor power, reactor type, time of irradiation, separation method, and time since separation. The signatures include plutonium isotopic mass ratios, plutonium isotopic activity ratios, and transplutonium isotope ratios. Separation signatures include evaluation of Zr, Tc, Ru, and the lanthanides, with examples using Nd isotopics. Alloys of actinide metals as signatures is also presented. The lecture is 35 minutes. The lecture is assigned 3 December 2018 and due 8 December 2018.

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Notes
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PDF quiz (download to computer before answering)
PDF Quiz 12 Answers

Reading:  Glasstone and Dolan: Effects of Nuclear Weapons

Additional web links

  1. Nuclear Forensics Role, State of the Art, Program Needs
  2. Determination of the origin of unknown irradiated nuclear fuel
  3. Nuclear Forensics Analysis Book
  4. Who Did It? Using International Forensics to Detect and Deter Nuclear Terrorism
  5. Age determination of plutonium material in nuclear forensics by thermal ionisation mass spectrometry
  6. Origin determination of Pu material

     

  1. Forensic Radiochemistry Presentation by Moody
  2. Nuclear Forensics Science Article
  3. Nuclear forensics—a methodology providing clues on the origin of illicitly trafficked nuclear materials
  4. IAEA Nuclear Forensics Support
  5. Nuclear Forensics: Key to Ensuring Nuclear Security
  6. IAEA Advances in Nuclear Forensics
  7. NAS separations book

Julie Gostic, former UNLV Radiochemistry Graduate Student in Nuclear Forensics

US trains nuclear detectives to trace 'loose' nukes

last update: Sunday 7 October, 2018